2010 - Ph.D. (Physical Chemistry) The University of North Carolina at Chapel Hill
Dissertation "Using atomistic simulations to uncover microscopic details of nucleosomal electrostatics, energy landscapes of proteins and photovoltaic polymer dynamics."
2005 - B.S. (Chemistry) The Pennsylvania State University
Christopher K Materese
(Research AST, Planetary Studies)
christopher.k.materese@nasa.gov
Org Code: 691
NASA/GSFCMail Code: 691.1
Greenbelt, MD 20771
Employer: NASA
Positions/Employment
Research Scientist
NASA Goddard Spaceflight Center - Greenbelt, MD
August 2018 - Present
Research Scientist
BAER Institute/NASA Ames Research Center - Moffett Field, CA
July 2015 - August 2018
NASA Postdoctoral Fellow
Oak Ridge Associated Universities/NASA Ames Research Center - Moffett Field, CA
July 2012 - June 2015
Research Associate
SETI Institute/NASA Ames Research Center - Moffett Field, CA
July 2010 - June 2012
Graduate Student Researcher
The University of North Carolina at Chapel Hill - Chapel Hill, NC
July 2005 - June 2010
Education
Professional Service
Manuscript reviewer for professional journals including the Astrophysical Journal, Astronomy & Astrophysics, Accounts of Chemical Research, ACS Earth and Space Chemistry, Nature Communications, Science Advances, and Astrobiology.
Regular proposal reviewer for funding programs at NASA
Grants
Quantifying the Radiolytic Stability of Aromatic Nitrogen Heterocycles
Astrophysics Research and Analysis 2021 - NASA - Awarded: 2022-05-14
Assessing Parent Body Processing of Amino Acids from Ice Radiation Experiments
Emerging Worlds 2019 - NASA - Awarded: 2019-11-04
Rates of Radiation Induced Deuterium/Hydrogen Exchange in Organic Molecules Embedded in Water Ice: Evaluating the Importance of Ice Radiation Chemistry in Observed Isotopic Ratios.
Solar System Workings 2018 - NASA - Awarded: 2019-09-27
Talks, Presentations and Posters
Invited
Formation and destruction of nucleobases in ices
July 2020
American Vacuum Society Seminar Series hosted by the University of Central Florida (oral presentation)
Could polycyclic aromatic hydrocarbons with excess peripheral H atoms (Hn-PAHs) be responsible for anomalous 3.4 micron emission bands in protoplanetary nebulae?
2018
SOFIA Community tele-talk series (oral presentation)
Other
The Radiolytic Stability of Thymine in Water Ice
November 2020
Division for Planetary Science (2020) virtual conference (e-poster)
The Stability of Nucleobases Against Radiolytic Destruction in Water Ice
July 2019
Astrobiology Science Conference, Seattle, Wa. (poster)
Laboratory Studies of the Radiolytic Destruction of Nucleobases in Icy Environments
May 2019
IAU 350, Cambridge University, Cambridge, UK (poster)
Publications
Refereed
Qasim, D., H. L. McLain, J. C. Aponte, et al. D. P. Glavin, J. P. Dworkin, and C. K. Materese. 2023. Meteorite Parent Body Aqueous Alteration Simulations of Interstellar Residue Analogs ACS Earth and Space Chemistry 7 (1): 156-167 [10.1021/acsearthspacechem.2c00274]
Materese, C. K. 2022. Radiation-induced D-to-H Exchange in Ices Containing Ethane or Benzene: Reactions and Rate Constants The Astrophysical Journal 941 (1): 94 [10.3847/1538-4357/ac9d3a]
Qasim, D., R. L. Hudson, and C. K. Materese. 2022. Radiation-induced D/H Exchange Rate Constants in Aliphatics Embedded in Water Ice The Astrophysical Journal 929 (2): 7 [10.3847/1538-4357/ac602b]
Nuevo, M., E. Sciamma-O’Brien, S. A. Sandford, et al. F. Salama, C. K. Materese, and A. D. Kilcoyne. 2022. The Titan Haze Simulation (THS) experiment on COSmIC. Part III. XANES study of laboratory analogs of Titan tholins Icarus 376 114841 [10.1016/j.icarus.2021.114841]
Materese, C. K., P. A. Gerakines, and R. L. Hudson. 2021. Laboratory Studies of Astronomical Ices: Reaction Chemistry and Spectroscopy Accounts of Chemical Research 54 (2): 280-290 [10.1021/acs.accounts.0c00637]
Materese, C. K., M. Nuevo, S. A. Sandford, P. P. Bera, and T. J. Lee. 2020. The Production and Potential Detection of Hexamethylenetetramine-Methanol in Space Astrobiology 20 (5): 601-616 [10.1089/ast.2019.2147]
Materese, C. K., P. A. Gerakines, and R. L. Hudson. 2020. The Radiation Stability of Thymine in Solid H2O Astrobiology 20 (10): 956-963 [10.1089/ast.2019.2199]
Sandford, S. A., E. Bierhaus, P. Antreasian, et al. J. Leonard, C. K. Materese, C. W. May, J. T. Songer, J. P. Dworkin, D. S. Lauretta, and B. Rizk. 2019. Outgassing from the OSIRIS-REx Sample Return Capsule: Characterization and Mitigation Acta Astronautica 166 391-399 [10.1016/j.actaastro.2019.07.043]
Cruikshank, D., C. Materese, Y. Pendleton, et al. P. Boston, W. Grundy, B. Schmitt, C. Lisse, K. Runyon, J. Keane, R. Beyer, M. Summers, F. Scipioni, S. Stern, C. Dalle Ore, C. Olkin, L. Young, K. Ennico, H. Weaver, and V. Bray. 2019. Prebiotic Chemistry of Pluto Astrobiology 19 (7): 831-848 [10.1089/ast.2018.1927]
Materese, C. K., M. Nuevo, B. L. McDowell, C. E. Buffo, and S. A. Sandford. 2018. The Photochemistry of Purine in Ice Analogs Relevant to Dense Interstellar Clouds The Astrophysical Journal 864 (1): 44 [10.3847/1538-4357/aad328]
Materese, C. K., J. D. Bregman, and S. A. Sandford. 2017. The Detection of 6.9 μm Emission Features in the Infrared Spectra of IRAS 04296+3429, IRAS 05341+0852, and IRAS 22272+5435: Evidence for the Presence of Hn-PAHs in Post-AGB Stars The Astrophysical Journal 850 (2): 165 [10.3847/1538-4357/aa960d]
Materese, C. K., M. Nuevo, and S. A. Sandford. 2017. The Formation of Nucleobases from the Ultraviolet Photoirradiation of Purine in Simple Astrophysical Ice Analogues Astrobiology 17 (8): 761-770 [10.1089/ast.2016.1613]
Bera, P. P., M. Nuevo, C. K. Materese, S. A. Sandford, and T. J. Lee. 2016. Mechanisms for the formation of thymine under astrophysical conditions and implications for the origin of life The Journal of Chemical Physics 144 (14): 144308 [10.1063/1.4945745]
Materese, C. K., D. P. Cruikshank, S. A. Sandford, H. Imanaka, and M. Nuevo. 2015. ICE CHEMISTRY ON OUTER SOLAR SYSTEM BODIES: ELECTRON RADIOLYSIS OF N2-, CH4-, AND CO-CONTAINING ICES The Astrophysical Journal 812 (2): 150 [10.1088/0004-637x/812/2/150]
Materese, C. K., M. Nuevo, and S. A. Sandford. 2015. N- ANDO-HETEROCYCLES PRODUCED FROM THE IRRADIATION OF BENZENE AND NAPHTHALENE IN H2O/NH3-CONTAINING ICES The Astrophysical Journal 800 (2): 116 [10.1088/0004-637x/800/2/116]
Nuevo, M., C. K. Materese, and S. A. Sandford. 2014. THE PHOTOCHEMISTRY OF PYRIMIDINE IN REALISTIC ASTROPHYSICAL ICES AND THE PRODUCTION OF NUCLEOBASES The Astrophysical Journal 793 (2): 125 [10.1088/0004-637x/793/2/125]
Materese, C. K., D. P. Cruikshank, S. A. Sandford, et al. H. Imanaka, M. Nuevo, and D. W. White. 2014. ICE CHEMISTRY ON OUTER SOLAR SYSTEM BODIES: CARBOXYLIC ACIDS, NITRILES, AND UREA DETECTED IN REFRACTORY RESIDUES PRODUCED FROM THE UV PHOTOLYSIS OF N2:CH4:CO-CONTAINING ICES The Astrophysical Journal 788 (2): 111 [10.1088/0004-637x/788/2/111]
Sandford, S. A., P. P. Bera, T. J. Lee, C. K. Materese, and M. Nuevo. 2014. Photosynthesis and Photo-Stability of Nucleic Acids in Prebiotic Extraterrestrial Environments Topics in Current Chemistry 123-164 [10.1007/128_2013_499]
Materese, C. K., M. Nuevo, P. P. Bera, T. J. Lee, and S. A. Sandford. 2013. Thymine and Other Prebiotic Molecules Produced from the Ultraviolet Photo-Irradiation of Pyrimidine in Simple Astrophysical Ice Analogs Astrobiology 13 (10): 948-962 [10.1089/ast.2013.1044]
Sandford, S. A., M. P. Bernstein, and C. K. Materese. 2013. THE INFRARED SPECTRA OF POLYCYCLIC AROMATIC HYDROCARBONS WITH EXCESS PERIPHERAL H ATOMS (Hn-PAHs) AND THEIR RELATION TO THE 3.4 AND 6.9 μm PAH EMISSION FEATURES The Astrophysical Journal Supplement Series 205 (1): 8 [10.1088/0067-0049/205/1/8]
Wilger, D. J., S. E. Bettis, C. K. Materese, et al. M. Minakova, G. A. Papoian, J. M. Papanikolas, and M. L. Waters. 2012. Tunable Energy Transfer Rates via Control of Primary, Secondary, and Tertiary Structure of a Coiled Coil Peptide Scaffold Inorganic Chemistry 51 (21): 11324-11338 [10.1021/ic300669t]
Savelyev, A., C. K. Materese, and G. A. Papoian. 2011. Is DNA’s Rigidity Dominated by Electrostatic or Nonelectrostatic Interactions? J. Am. Chem. Soc. 133 (48): 19290-19293 [10.1021/ja207984z]
Materese, C. K., A. Savelyev, and G. A. Papoian. 2009. Counterion Atmosphere and Hydration Patterns near a Nucleosome Core Particle Journal of the American Chemical Society 131 (41): 15005-15013 [10.1021/ja905376q]
Zhuravlev, P. I., C. K. Materese, and G. A. Papoian. 2009. Deconstructing the Native State: Energy Landscapes, Function, and Dynamics of Globular Proteins The Journal of Physical Chemistry B 113 (26): 8800-8812 [10.1021/jp810659u]
Materese, C. K., C. C. Goldmon, and G. A. Papoian. 2008. Hierarchical organization of eglin c native state dynamics is shaped by competing direct and water-mediated interactions Proceedings of the National Academy of Sciences 105 (31): 10659-10664 [10.1073/pnas.0801850105]
Luellen, B. A., M. E. Szapacs, C. K. Materese, and A. M. Andrews. 2006. The neurotoxin 2′-NH2-MPTP degenerates serotonin axons and evokes increases in hippocampal BDNF Neuropharmacology 50 (3): 297-308 [10.1016/j.neuropharm.2005.09.006]